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缸套在燃烧冲击和活塞敲击激励下会产生接近表面粗糙度的动态变形,极有可能影响缸套-活塞环组件间的摩擦润滑过程。为了研究缸套动态变形潜在的影响,将动力学仿真获取的缸套内表面的动态变形经过处理后导入到润滑模型中,同时采用数值积分计算的方式对油液压力应力因子和剪切应力因子进行实时计算求解,使仿真计算更加符合实际情况。通过搭建同时考虑缸套变形与油液剪切特性影响的改进润滑模型,计算得到整个工作循环内活塞环上的最小油膜厚度和摩擦力曲线。结果表明:考虑缸套动态变形后的最小油膜厚度和摩擦力曲线出现了明显的波动,而且考虑缸套动态变形后的摩擦力比未考虑之前出现了明显下降。 相似文献
44.
Antonio Buonerba Francesco Della Monica Vito Speranza Carmine Capacchione Stefano Milione Alfonso Grassi 《Polymer International》2019,68(10):1681-1687
The thin‐film morphology of stereoregular syndiotactic poly(p‐methylstyrene)–(cis‐1,4‐polybutadiene) (sP(pMS–B)) multiblock copolymers has been investigated using tapping mode atomic force microscopy with variation of the polymer composition and monomer block lengths. The morphology of the thin films ranges from isolated circular domains of sP(pMS) embedded into a matrix of polybutadiene (PB) to isolated domains of PB embedded into a matrix of sP(pMS), passing through bicontinuous (jagged) lamellae when the pMS concentration is in the range 20–67 mol%. Multiple folding of the polymer segments, i.e. where reciprocal inclusions of polymer segments to each other phase are able to generate greater domain, has been postulated and validated by considerations on the polymer architecture and the thermal and crystalline behaviour. © 2019 Society of Chemical Industry 相似文献
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《International Journal of Hydrogen Energy》2021,46(73):36201-36209
A novel three-dimensional (3D) core-shell nanostructure decorated with plasmonic Au nanoparticles (NPs) was prepared for photoelectrochemical water splitting. In the new nanostructure, ZnO nanorods (NRs) are perpendicular to ZnO nanosheets (NSs), and the ZnO NSs-NRs are coated with a thin TiO2 shell formed by liquid phase deposition. The plasmonic Au NPs were formed in situ on the surface of ZnO NSs-NRs@TiO2 by thermal reduction. A thin TiO2 shell and uniformly distributed Au NPs were successfully obtained. The photoconversion efficiency and photocurrent density of the 3D ZnO NSs-NRs@TiO2-Au nanostructure respectively reached 0.48% and 1.73 mA cm−2 at 1.23 V vs. reversible hydrogen electrode, 4.80 and 4.33 times higher than those of ZnO NSs, respectively. The thin TiO2 shell effectively promoted charge separation, while the surface plasmon resonance effects of the Au NPs improved the photocurrent density. The findings suggest that the 3D ZnO NSs-NRs@TiO2-Au nanostructure is a promising photoanode for photoelectrochemical water splitting. 相似文献
47.
Irshad Ahmad Shazia Shukrullah Muhammad Yasin Naz Muhammad Athar Rasheed Mukhtar Ahmad Ejaz Ahmed Muhammad Shoaib Akhtar N.R. Khalid Abid Hussain Sadia Khalid 《International Journal of Hydrogen Energy》2021,46(53):26711-26724
CNTs were decorated onto Sr doped ZnO nanoparticles to construct an efficient photocatalyst via a facile sol-gel method. The as-fabricated Sr doped ZnO/CNTs with recyclability exhibits Sr and CNTs content dependent hydrogen evolution activit under visible light illumination. The Sr doped ZnO/CNTs photocatalyst shows the highest hydrogen evolution rate of 2732.2 μmolh?1g?1, which is 33.7 and 2.83 times higher than pure ZnO and Sr doped ZnO photocatalysts, respectively. The improved hydrogen evolution activity of Sr doped ZnO/CNTs is primarily assigned to high surface area, Sr doping and construction of heterojunction, which can extend the light absorption, decrease the optical band gap and improve the charge separation. Moreover, the underlying photocatalytic mechanism is proposed on the basis of Mott-Schottky study and explains the interfacial charge transfer process from ZnO to CNTs and Sr. This work open new strategies to synthesize CNTs based nanocomposite for hydrogen evolution. 相似文献
48.
Guomin Yu Pei Tian Kexin Ren Wenchao Wu Zhenxi Zhang Zhenbin Gong Junyan Zhang 《Ceramics International》2021,47(15):21325-21333
The establishment of superlow friction in moist air is very important for the engineering application of hydrogenated diamond-like carbon (H-DLC) films. Nevertheless, water molecules in the surrounding atmosphere always result in the failure of the near-frictionless state. This work aims to explore the effects of water molecules in the environment and the material of the counterparts on the tribological performance of a composite structure prepared by depositing MoS2 on a H-DLC film. The results indicated that the existence of water molecules in the atmosphere is beneficial for achieving stable superlubricity for the material system because it helps retain the in-situ formed MoS2 transfer film on the counterpart. In the presence of water molecules, the wear interface was replaced by a robust and incommensurate MoS2 tribolayer/H-DLC sliding interface, which was responsible for the superlow friction achieved in this work. The results also revealed that the ZrO2 counterpart was capable of retaining the as-formed MoS2 transfer film and establishing long-lasting superlow friction even in dry air. The mechanisms behind this phenomenon are also discussed in this paper. 相似文献
49.
《Ceramics International》2021,47(20):28505-28510
Micro-columnar structured europium doped lutecia (Lu2O3:Eu) scintillation film is one of the most attractive candidate materials for high-energy hard X-ray imaging detectors because of their excellent physical, scintillation properties and light guide effect. Lu2O3:Eu micro-columnar film (MCF) with 9 μm thickness was obtained on a yttrium stabilized zirconia (YSZ) (100) single crystal substrate by laser chemical vapor deposition (LCVD), and its structure, morphology, photoluminescence and scintillation properties were characterized. The structure and morphology of obtained film were investigated by grazing incidence X-ray diffraction (GIXRD) and scan electron microscopy (SEM). The photoluminescence and scintillation properties, including photoluminescence excitation (PLE), photoluminescence (PL), PL decay, X-ray excited luminescence (XEL), were measured and discussed. The X-ray imaging result of Lu2O3:Eu MCF on YSZ substrate was obtained for the first time and spatial resolution of 2 μm was obtained at BL13W beamline at Shanghai synchrotron radiation facility (SSRF). 相似文献
50.
Jiadong Liu Di Yu Zhipeng Zheng Geng Huangfu Yiping Guo 《Ceramics International》2021,47(3):3573-3579
Constructing hybrid nanogenerators (NGs) based on triboelectric effect and piezoelectric effect can combine the merits of the individual type of NG thus have drawn great attention in flexible wearable electronics. Herein, we prepared flexible BiFeO3 (BFO) film in a simple and cost-effective way, which was used to fabricate a wearable hybrid piezoelectric-triboelectric nanogenerator (H–P/TENG) with silk fiber. By optimizing the experimental conditions, the highest open-circuit voltage of 110 V and short-circuit current density of 3.67 μA/cm2 were achieved under 1 Hz contact-separation movement. The device also showed the best output power density of 151.42 μW/cm2 with load resistance of 250 MΩ. Stimulating by moving body, the fabricated H–P/TENG successively realized the harvest and conversion of mechanical energy into electric energy, demonstrating great potential to monitor posture and establish a self-powered system. Moreover, the proposed H–P/TENG exhibited great stable output after 1800 contact-separation cycles, indicating the outstanding structure stability and fatigue resistance. This work will provide not only a facile and viable way to realize the application of ferroelectric materials in H–P/TENG but also new opportunities for developing monitor posture and self-powered systems. 相似文献